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It is suggested that analysis of sedimentary pyrite from the Belingwe sedimentary basin in Zimbabwe may provide evidence for bacterial reduction at this date.
2,500,000,000 to 542,000,000 years ago The Proterozoic Eon: the most recent part of the Precambrian Supereon.
"Among the most attractive of these" tree-fern once called Cyelopteris (Round-leaved Fern), re named Palasopteris Hibernicus (Primitive Irish Fern). It was the "monarch of the primeval forests" whose "graceful fronds bent over the clear waters of a lake".
The end-Frasnian extinction (the largest) about 375 million years ago.